Synthesis and structures of isomerically pure bis-(alkylbenzo) crown ethers

被引：11

作者：

Sachleben, RA

Bryan, JC

Lavis, JM

Starks, CM

Burns, JH

机构：

[1] Chem. and Analyt. Sciences Division, Oak Ridge National Laboratory, MS-6119/4500S, Oak Ridge, TN 37831-6119

来源：

TETRAHEDRON | 1997年 / 53卷 / 40期

关键词：

D O I：

10.1016/S0040-4020(97)00932-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient method for the synthesis of bis-(4-alkyl-2-hydroxyphenoxy) alkoxy ethers, precursors to highly lipophilic, alkylbenzo-substituted crown ethers, is described. Thirteen isomerically-pure, bis-t-alkylbenzo crown ethers were prepared. The solid-state structures of three representative, bis-t-octylbenzo crown ethers are reported, representing the first structures ever reported for t-octylbenzocrown ethers. Published by Elsevier Science Ltd.

引用

页码：13567 / 13582

页数：16

共 36 条

[1] STEREOSPECIFIC SYNTHESES OF MACROBICYCLIC POLYETHERS WITH CARBON BRIDGEHEADS FROM CHIRAL GLYCEROL DERIVATIVES [J].

ALLWOOD, BL ;

FULLER, SE ;

NING, PCYK ;

SLAWIN, AMZ ;

STODDART, JF ;

WILLIAMS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (20) :1356-1360

[2] Synthesis and structures of nitromethane complexes of furanotribenzo-21-crown-7 and dibenzo-21-crown-7 [J].

Burns, JH ;

Bryan, JC ;

Davis, MC ;

Sachleben, RA .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1996, 26 (04) :197-207

[3] CRYSTAL-STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .4. CRYSTAL-STRUCTURES OF DIBENZO-30-CROWN-10 (2,3-17,18-DIBENZO-1,4,7,10,13,16,19,22,25,28-DECAOXACYCLOTRIACONTA-2,17-DIENE) AND OF ITS COMPLEX POTASSIUM IODIDE [J].

BUSH, MA ;

TRUTER, MR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1972, (03) :345-&

[4] STABILIZING ROLE OF INCLUDED SOLVENT IN TERNARY COMPLEXATION - SYNTHESIS, STRUCTURES AND THERMAL ANALYSES OF 3 18-CROWN-6 SULFONAMIDE ACETONITRILE INCLUSION-COMPOUNDS [J].

CAIRA, MR ;

MOHAMED, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1993, 49 :760-768

[5] SYNTHESIS AND ION BINDING OF SYNTHETIC MULTIDENTATE MACROCYCLIC-COMPOUNDS [J].

CHRISTENSEN, JJ ;

EATOUGH, DJ ;

IZATT, RM .

CHEMICAL REVIEWS, 1974, 74 (03) :351-384

[6]

Cox B. G., 1992, COORDINATION TRANSPO

[7] STRUCTURE OF THE BENZYLAMMONIUM PERCHLORATE COMPLEX OF 3,6,9,12,15,18,21,26-OCTAOXABICYCLO[21.2.1]HEXACOSA-1(25),23-DIENE-2,22-DIONE [J].

DALLEY, NK ;

BRADSHAW, JS ;

LARSON, SB ;

SIMONSEN, SH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (JUN) :1859-1862

[8]

DENG Y, 1995, J CHEM SOC FARADAY T, V23, P4215

[9]

DIETZ ML, COMMUNICATION

[10] ALKALINE-EARTH METAL-COMPLEXES OF FURANYL-CONTAINING SCHIFF-BASE MACROCYCLES - X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF STRONTIUM COMPLEX [J].

FENTON, DE ;

COOK, DH ;

NOWELL, IW ;

WALKER, PE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (18) :623-624

← 1 2 3 4 →