Direct observation of chiral metal-organic complexes assembled on a Cu(100) surface

被引：146

作者：

Messina, P

Dmitriev, A

Lin, N

Spillmann, H

Abel, M

Barth, JV

Kern, K

机构：

[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

[2] Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 47期

关键词：

D O I：

10.1021/ja028553s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report single-molecule level STM observations of chiral complexes generated by the assembly of achiral components at a metal surface. Following co-deposition of iron atoms and 1,3,5-tricarboxylic benzoic acid (trimesic acid, TMA) on Cu(100) in ultrahigh vaccum, TMA molecules react with the metal centers, and metal-ligand interactions stabilize R and S chiral complexes which are clearly distinguished by STM. Copyright © 2002 American Chemical Society.

引用

页码：14000 / 14001

页数：2

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