Metal complexes of chelating diarylamido phosphine ligands

被引:244
作者
Liang, LC [1 ]
机构
[1] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 80424, Taiwan
[2] Natl Sun Yat Sen Univ, Ctr Nonosci & Nonotechnol, Kaohsiung 80424, Taiwan
关键词
amido phosphine ligands; diarylamido phosphine ligands; hybrid ligands; main-group metal; pincer ligands; transition metal;
D O I
10.1016/j.ccr.2006.01.001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review summarizes the recent progress in coordination and organometallic chemistry involving metal complexes of chelating diarylamido phosphine ligands, including bidentate amido phosphine [NP](-), tridentate amido diphosphine [PNP](-), and tridentate diamido phosphine [NPN](2-). Consistent with the anticipated hybrid characteristic of the ligands, diarylamido phosphine complexes that have been characterized thus far involve both soft and hard main-group and transition metals. The inherent rigidity and robustness imposed by the o-phenylene backbone of the ligands are beneficial to the development of reaction chemistry of these diarylamido phosphine complexes. Preparation of the ligand precursors and the corresponding metal complexes and the subsequent reactivity studies are discussed. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1152 / 1177
页数:26
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