Electrochemistry of encapsulated redox centers

被引：146

作者：

Cardona, CM

Mendoza, S

Kaifer, AE ^{[1
]}

机构：

[1] Univ Miami, Ctr Supramol Sci, Coral Gables, FL 33124 USA

[2] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2000年 / 29卷 / 01期

关键词：

D O I：

10.1039/a804241a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A few examples of molecules containing a redox active core surrounded by an organic sheath have been synthesized recently. The redox nucleus may be attached covalently to the structure's core or held there by noncovalent forces. This review article surveys the electrochemical behavior of such redox centers, emphasizing the thermodynamic and kinetic effects brought about by encapsulation.

引用

页码：37 / 42

页数：6

共 31 条

[1] Designing dendrimers based on transition metal complexes. Light-harvesting properties and predetermined redox patterns
Balzani, V
Campagna, S
Denti, G
Juris, A
Serroni, S
Venturi, M
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (01) : 26 - 34
[2] Molecular machines
Balzani, V
Gómez-López, M
Stoddart, JF
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (07) : 405 - 414
[3] Bowden E.F., 1997, INTERFACE, V6, P40
[4] Asymmetric redox-active dendrimers containing a ferrocene subunit. Preparation, characterization, and electrochemistry
Cardona, CM
Kaifer, AE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (16) : 4023 - 4024
[5] Dioxygen and carbon monoxide binding in dendritic iron(II)porphyrins
Collman, JP
Fu, L
Zingg, A
Diederich, F
[J]. CHEMICAL COMMUNICATIONS, 1997, (02) : 193 - 194
[6] Self-assembling capsules
Conn, MM
Rebek, J
[J]. CHEMICAL REVIEWS, 1997, 97 (05) : 1647 - 1668
[7] SYNTHESIS AND ELECTROCHEMICAL PROPERTIES OF REDOX-ACTIVE [2]ROTAXANES BASED ON THE INCLUSION COMPLEXATION OF 1,4-PHENYLENEDIAMINE AND BENZIDINE BY CYCLOBIS(PARAQUAT-P-PHENYLENE)
CORDOVA, E
BISSELL, RA
KAIFER, AE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (04) : 1033 - 1038
[8] Cram D.J., 1994, MONOGRAPHS SUPRAMOLE, V4
[9] DANDLIKER PJ, 1994, ANGEW CHEM INT EDIT, V33, P1739, DOI 10.1002/anie.199417391
[10] Dendrimers with porphyrin cores: Synthetic models for globular heme proteins
Dandliker, PJ
Diederich, F
Zingg, A
Gisselbrecht, JP
Gross, M
Louati, A
Sanford, E
[J]. HELVETICA CHIMICA ACTA, 1997, 80 (06) : 1773 - 1801

← 1 2 3 4 →