An efficient approach to bridged-bicyclic rings via intramolecular diazo ketone insertion

被引:6
作者
Chen, L [1 ]
Zhang, XQ [1 ]
Schultz, A [1 ]
机构
[1] Rensselaer Polytech Inst, Dept Chem, Troy, NY 12180 USA
基金
美国国家卫生研究院;
关键词
D O I
10.1016/S0040-4039(02)00878-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A regioselective intramolecular diazo ketone insertion reaction of chiral cyclohexenones is described. The methodology shows potential utility in the syntheses of bicyclo[4.2.1]nonan-9-one, bicyclo[4.3.1]decan-10-one and cyclooctanoid rings. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4711 / 4715
页数:5
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