We present measurements obtained with the Spitzer Space Telescope in five bands from 3.6 to 24 mm of the northern inner radio lobe of Centaurus A, the nearest powerful radio galaxy. We show that this emission is synchrotron in origin. Comparison with ultraviolet observations from GALEX shows that diffuse ultraviolet emission exists in a smaller region than the infrared but also coincides with the radio jet. We discuss the possibility that synchrotron emission is responsible for the ultraviolet emission, and we conclude that further data are required to confirm this.