Alkali-metal complexes of a tetramethylcyclopentadienyl-functionalized pyrazolylborate ligand.: Structures of [Li2(THF)3B(3-Mepz)3(C5Me4)] and [K2(THF)2B(3-MepZ)3(C5Me4)]∞

被引：10

作者：

Roitershtein, D ^{[1
]}

Domingos, A ^{[1
]}

Marques, N ^{[1
]}

机构：

[1] ITN, Dept Quim, P-2686953 Sacavem, Portugal

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 14期

关键词：

D O I：

10.1021/om0498293

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new dianionic ligand [B(3-Mepz)(3)(C5Me4)](2-) was prepared and structurally characterized as its lithium and potassium salts. In the solid state, [Li-2(THF)(3){B(3-Mepz)(3)}(C5Me4)] is monomeric, while [K-2(THF)(2){B(3-Mepz)(3)}C5Me4)](infinity) consists of infinite puckered chains. The compounds were synthesized by reaction of B(NMe2)(2)(C5Me4H) with 2 equiv of 3-methylpyrazole and 1 equiv of M(3-Mepz) (M = Li, K) followed by deprotonation with n-BuLi or KH. The crystal structure of the intermediate monoanion, [Li(THF)(2){B(3-Mepz)(3)}-(C5Me4H)], is also presented.

引用

页码：3483 / 3487

页数：5

共 32 条

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