Recycling of dry and wet polyamide 6

被引:62
作者
La Mantia, FP [1 ]
Curto, D [1 ]
Scaffaro, R [1 ]
机构
[1] Univ Palermo, Dipartimento Ingn Chim Proc & Mat, I-90128 Palermo, Italy
关键词
D O I
10.1002/app.11136
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Recycling of polycondensation polymers can give rise to secondary materials with good mechanical properties only if a careful drying is carried out before the melt reprocessing operations. The presence of humidity provokes the hydrolytic chain scission of the macromolecules and the consequent decrease of molecular weight and properties. In this work, the drying stop was substituted by the addition of an antioxidant that is able to protect the macromolecules because it is the autioxidant is more prone to hydrolysis, thus removing the water from the melt. The mechanical properties of polyamide 6 reprocessed more times in wet conditions and in the presence of this stabilizer are even better than those obtained reprocessing the dry polyamide. (C) 2002 Wiley Periodicals, Inc.
引用
收藏
页码:1899 / 1903
页数:5
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