Ordered mesoporous and microporous molecular sieves functionalized with transition metal complexes as catalysts for selective organic transformations

被引:1002
作者
De Vos, DE [1 ]
Dams, M [1 ]
Sels, BF [1 ]
Jacobs, PA [1 ]
机构
[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium
关键词
D O I
10.1021/cr010368u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reactions catalyzed by transition metal complexes, immobilized on zeolites or ordered mesoporous and microporous molecular sieves was reviewed. Many strategies for immobilization of metal complexes on ordered porous inorganic matrices was demonstrated. The ion exchange capacity or the cage structure of zeolites was exploited to immobilize metal complexes via electrostatic interactions or by entrapment.
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页码:3615 / 3640
页数:26
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