Gold supported on iron oxy-hydroxides: a versatile tool for the synthesis of fine chemicals

被引：22

作者：

Milone, C. ^{[1
]}

Ingoglia, R. ^{[1
]}

Galvagno, S. ^{[1
]}

机构：

[1] Univ Messina, Dept Ind Chem & Mat Engn, Fac Engn, I-98166 Messina, Italy

来源：

GOLD BULLETIN | 2006年 / 39卷 / 02期

关键词：

gold catalysts; selective hydrogenation; selective oxidation; hydrogen peroxide; alpha; beta unsaturated alcohols; iron oxy-hydroxides;

D O I：

10.1007/BF03215277

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A comprehensive overview on gold supported on iron oxy-hydroxides as tool for the synthesis of fine chemicals is given. We will discuss on the catalytic activity of gold supported on iron oxy-hydroxides in several reactions of potential industrial interest, comprising the selective oxidation of primary alcohol to aldehyde, the selective reduction of alpha,beta unsaturated aldehydes and ketones to the corresponding (alpha,beta unsaturated alcohols. Furthermore, a significant application of gold supported on iron oxy-hydroxides is the direct synthesis of hydrogen peroxide from H-2 and O-2. The versatility showed by Au supported on oxy-hydroxides catalysts is an aspect of great importance for industrial applications.

引用

页码：54 / 65

页数：12

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