Crystallization of Bi4Ti3O12 from glasses in the system Bi2O3/TiO2/B2O3

被引：60

作者：

Gerth, K ^{[1
]}

Russel, C ^{[1
]}

机构：

[1] OTTO SCHOTT INST,D-07743 JENA,GERMANY

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1997年 / 221卷 / 01期

关键词：

Bismuth compounds - Boron compounds - Ceramic materials - Composition effects - Crystal microstructure - Crystallization - Extrusion - Ferroelectric materials - Heat treatment - Morphology - Titanium dioxide;

D O I：

10.1016/S0022-3093(97)00306-2

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The system Bi2O3-TiO2-B2O3 has a glass-forming region large compared to other ternary oxide systems, which enables the preparation of glasses possessing B2O3-contents as low as 25 mol%. During thermal treatment at temperatures in the range of 500 to 700 degrees C, the ferroelectric Bi4Ti3O12-phase is formed, In all compositions, after treatments at 600 degrees C, a maximum crystal content is obtained. The variation of the glass composition affects the micrcostructure: the smaller the content of B2O3, the smaller are the crystallites formed and the larger their quantity. Some of these glass ceramics contain crystals with plate-like morphology. This morphology should enable the preparation of oriented glass ceramics bl mechanical deformation processes, such as extruding. (C) 1997 Elsevier Science B.V.

引用

页码：10 / 17

页数：8

共 20 条

[1]

[Anonymous], 1979, GLASS CERAMICS

[2]

[Anonymous], 1992, GLASCHEMIE, DOI DOI 10.1007/978-3-662-07499-2

[3]

Arlt G., 1995, BOL SOC ESP CERAM V, V34, P267

[4]

AURIVILLIUS B, 1950, ARK KEMI, V1, P499

[5]

BISHOP WW, 1969, MEM GEOL SURV UGANDA, V10, P1

[6]

BRECHOWSTEICH SM, 1959, GLASTECH BER, V32, P437

[7]

DURSCHANG B, 1994, GLASTECH BER GLASS C, V67, P99

[8]

DURSCHANG BR, 1994, GLASTECH BER-GLASS, V67, P171

[9]

Habelitz S, 1997, GLASTECH BER-GLASS, V70, P86

[10]

Herbert J M, 1982, Ferroelectric Transducers and Sensors

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