Transport coefficients cadmium salt rejection in nanofiltration membrane

被引:63
作者
Ballet, GT [1 ]
Gzara, L [1 ]
Hafiane, A [1 ]
Dhahbi, M [1 ]
机构
[1] INRST, Lab Eau & Technol Membranaires, Hammam Lif 2050, Tunisia
关键词
nanofiltration; cadmium removal; charge exclusion; phenomenological parameters; Speigler-Kedem model;
D O I
10.1016/j.desal.2004.06.148
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Cadmium is one of the main toxic pollutants generated by industrial activities, Many methods have been used to remove cadmium from wastewater issued from these industries. In the present study removal of cadmium Cd(II) ions from aqueous streams was investigated through a nanofiltration membrane process. The retention was studied as a function of the counter-ions, the ionic force and pH. The transport through the TFCS membrane was described by irreversible thermodynamics. The well-known Speigler-Kedem model was applied in order to determine phenomenological parameters sigma and P, respectively, the reflection coefficient of the membrane and the solute permeability of ions. The convective and diffusive parts of the mass transfer were quantified.
引用
收藏
页码:369 / 376
页数:8
相关论文
共 18 条
[1]   Characterisation of nanofiltration membranes for predictive purposes - Use of salts, uncharged solutes and atomic force microscopy [J].
Bowen, WR ;
Mohammad, AW ;
Hilal, N .
JOURNAL OF MEMBRANE SCIENCE, 1997, 126 (01) :91-105
[2]   Extraction and separation of metal cations in solution by supported liquid membrane using lasalocid A as carrier [J].
Canet, L ;
Seta, P .
PURE AND APPLIED CHEMISTRY, 2001, 73 (12) :2039-2046
[3]   Purification of heterocyclic drug derivatives from concentrated saline solution by nanofiltration [J].
Capelle, N ;
Moulin, P ;
Charbit, F ;
Gallo, R .
JOURNAL OF MEMBRANE SCIENCE, 2002, 196 (01) :125-141
[4]   A phenomenological mass transfer approach in nanofiltration of halide ions for a selective defluorination of brackish drinking water [J].
Diawara, CK ;
Lô, SM ;
Rumeau, M ;
Pontie, M ;
Sarr, O .
JOURNAL OF MEMBRANE SCIENCE, 2003, 219 (1-2) :103-112
[5]   Separation of concentrated organic/inorganic salt mixtures by nanofiltration [J].
Freger, V ;
Arnot, TC ;
Howell, JA .
JOURNAL OF MEMBRANE SCIENCE, 2000, 178 (1-2) :185-193
[6]   Experimental analysis of negative salt rejection in nanofiltration membranes [J].
Gilron, J ;
Gara, N ;
Kedem, O .
JOURNAL OF MEMBRANE SCIENCE, 2001, 185 (02) :223-236
[7]   Removal of hexavalent chromium by nanofiltration [J].
Hafiane, A ;
Lemordant, D ;
Dhahbi, M .
DESALINATION, 2000, 130 (03) :305-312
[8]   Modelling the rejection of nanofiltration membranes using zeta potential measurements [J].
Hagmeyer, G ;
Gimbel, R .
SEPARATION AND PURIFICATION TECHNOLOGY, 1999, 15 (01) :19-30
[9]   PERMEABILITY OF COMPOSITE MEMBRANES .1. ELECTRIC CURRENT, VOLUME FLOW AND FLOW OF SOLUTE THROUGH MEMBRANES [J].
KEDEM, O ;
KATCHALSKY, A .
TRANSACTIONS OF THE FARADAY SOCIETY, 1963, 59 (488) :1918-&
[10]   Application of low pressure nanofiltration membranes for the recovery and reuse of dairy industry effluents [J].
Koyuncu, I ;
Turan, M ;
Topacik, D ;
Ates, A .
WATER SCIENCE AND TECHNOLOGY, 2000, 41 (01) :213-221