A novel mixed-valence complex containing CoII2CoIII2 molecular squares with 4,5-imidazoledicarboxylate bridges

被引:119
作者
Wang, CF
Gao, EQ [1 ]
He, Z
Yan, CH
机构
[1] Qufu Normal Univ, Dept Chem, Shandong 273165, Qufu, Peoples R China
[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[3] Peking Univ, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, Beijing 100871, Peoples R China
[4] E China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
关键词
D O I
10.1039/b315357f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A heterometallic complex, Na-2[(Co2Co2III)-Co-II(IDC3-)(4)(bipy)(4)] .12H(2)O (bipy = 2,2'-bipyridine), in which mixed-valence tetranuclear squares with imidazoledicarboxylate (IDC3-) linkers are tethered into a unique chain through disodium units, is hydrothermally synthesized and structurally and magnetically characterized.
引用
收藏
页码:720 / 721
页数:2
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