Synthesis and characterization of nanostrucl ured Li2MnO3 from nanostructured MnOOH precursors

被引:20
作者
Zhang, WX [1 ]
Liu, Y [1 ]
Yang, ZH [1 ]
Tang, SP [1 ]
Chen, M [1 ]
机构
[1] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
nanostructures; chemical synthesis; transmission electron microscopy; X-ray diffraction;
D O I
10.1016/j.ssc.2004.06.007
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Li2MnO3 with different nanostructures was synthesized through a solid-state reaction. MnOOH nanorods and nanowires prepared via the hydrothermal method were used as precursors, respectively, to react with Li(OH)(H2O)-H-. to prepare nanostructured Li2MnO3 in the temperature range from 500 to 800 T. The samples were characterized by XRD, TEM, ESR and FTIR results. Based on the experimental results, the dehydration-oxidation-combination (DOC) formation mechanism of Li2MnO3 was proposed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:441 / 445
页数:5
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