Enhancement of Pt utilization in electrocatalysts by using gold nanoparticles

被引:214
作者
Zhao, Dan [1 ]
Xu, Bo-Qing [1 ]
机构
[1] Tsing Hua Univ, Dept Chem, Innovat Catalysis Program, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
关键词
cyclic voltammetry; electrochemistry; heterogeneous catalysis; nanostructures; platinum;
D O I
10.1002/anie.200600155
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Full employment of a Pt catalyst is reached by depositing very small (≤ 1.0 nm) Pt particles onto Au nanoparticles of about 10 nm in diameter (see picture) then loading the Pt∧Au particles onto a conventional carbon support. Data obtained from the electrooxidation of methanol demonstrate that every Pt atom assumes the function of an active site for electrocatalysis. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4955 / 4959
页数:5
相关论文
共 34 条
[1]   Colloidal gold aerogels: Preparation, properties, and characterization [J].
Anderson, ML ;
Morris, CA ;
Stroud, RM ;
Merzbacher, CI ;
Rolison, DR .
LANGMUIR, 1999, 15 (03) :674-681
[2]  
Anderson ML, 2002, NANO LETT, V2, P235, DOI 10.1021/n1015707d
[3]   The effect of the particle size on the kinetics of CO electrooxidation on high surface area Pt catalysts [J].
Arenz, M ;
Mayrhofer, KJJ ;
Stamenkovic, V ;
Blizanac, BB ;
Tomoyuki, T ;
Ross, PN ;
Markovic, NM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (18) :6819-6829
[4]   COMPARISON OF GAS-PHASE AND ELECTROCHEMICAL MEASUREMENTS FOR CHEMISORBED CARBON-MONOXIDE AND HYDROGEN ON PLATINUM CRYSTALLITES [J].
BETT, J ;
KINOSHIT.K ;
ROUTSIS, K ;
STONEHAR.P .
JOURNAL OF CATALYSIS, 1973, 29 (01) :160-168
[5]   Catalysis by gold [J].
Bond, GC ;
Thompson, DT .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1999, 41 (3-4) :319-388
[6]  
Bönnemann H, 2001, EUR J INORG CHEM, P2455
[7]  
BOUDART M, 1984, KINETICS HETEROGENEO, pCH1
[8]   Kinetically controlled Pt deposition onto self-assembled Au colloids: Preparation of Au (core)-Pt (shell) nanoparticle assemblies [J].
Cao, LY ;
Tong, LM ;
Diao, P ;
Zhu, T ;
Liu, ZF .
CHEMISTRY OF MATERIALS, 2004, 16 (17) :3239-3245
[9]  
Carrette L, 2000, CHEMPHYSCHEM, V1, P162, DOI 10.1002/1439-7641(20001215)1:4<162::AID-CPHC162>3.0.CO
[10]  
2-Z