Crystal structures and excimer fluorescence of anisoylbenzoylmethanatoboron and dianisoylmethanatoboron difluorides

被引:47
作者
Mirochnik, AG [1 ]
Bukvetskii, BV [1 ]
Fedorenko, EV [1 ]
Karasev, VE [1 ]
机构
[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia
关键词
fluorescence; crystal structure; X-ray diffraction analysis; excimer; beta-diketonatoboron difluorides;
D O I
10.1023/B:RUCB.0000030800.71663.7a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structures and spectral-luminescence properties of anisoylbenzoylmethanatoboron difluoride (1) and dianisoylmethanatoboron difluoride (2) were studied in the solid state and in solution. The structural features of Compounds 1 and 2 are responsible for the Occurrence of a new type of excimers in Solutions, which differs from that observed in the crystalline state.
引用
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页码:291 / 296
页数:6
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