A new class of single-molecule magnet:: [Mn9O7(OAc)11(thme)(py)3(H2O)2] with an S=17/2 ground state

被引：101

作者：

Brechin, EK

Soler, M

Davidson, J

Hendrickson, DN

Parsons, S

Christou, G

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[3] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[4] Univ Calif San Diego, Dept Chem, La Jolla, CA 92093 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 19期

关键词：

D O I：

10.1039/b206386g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [Mn3O(OAc)(6)(py)(3)] with 1,1,1- tris(hydroxymethyl) ethane (H(3)thme) gives the Mn(IV)(3)Mn(III)(4)Mn(II)(2) complex [Mn9O7(OAc)(11)(thme)(py)(3)(H2O)(2)], which has an S = 17/2 ground state and displays strong out-of-phase signals in ac susceptibility studies that establish it as a new class of single-molecule magnet.

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页码：2252 / 2253

页数：2

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