Formation of a [1+1] metallomacrocycle from a heterotritopic ligand containing two terpy and one bipy metal-binding domains

被引：29

作者：

Smith, CB ^{[1
]}

Constable, EC ^{[1
]}

Housecroft, CE ^{[1
]}

Kariuki, BM ^{[1
]}

机构：

[1] Univ Birmingham, Sch Chem Sci, Birmingham B15 2TT, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 18期

关键词：

D O I：

10.1039/b205233d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the heterotritopic ligand L, which contains one bipy and two terpy metal-binding domains linked by a flexible spacer with iron(II) chloride results in the formation of a [1 + 1] metallomacrocycle.

引用

页码：2068 / 2069

页数：2

共 12 条

[1]

[Anonymous], 1993, SUPRAMOL CHEM

[2] HYPODENTATE LIGANDS - SYSTEMATIC APPROACHES TO COMPLEXES CONTAINING DIDENTATE 2,2'/6',2''-TERPYRIDINE (TERPY) AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RU(BIPY-N,N')(2)(TERPY-N,N')][PF6](2) AND [RU(BIPY-N,N')(2)(BTERPY-N,N')][PF6](2) (BIPY=2,2'-BIPYRIDINE, BTERPY=6-BROMO-2,2'/6',2''-TERPYRIDINE) [J].

CHOTALIA, R ;

CONSTABLE, EC ;

HANNON, MJ ;

TOCHER, DA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (22) :3571-3580

[3] SYNTHESIS AND COORDINATION BEHAVIOR OF 6',6''-BIS(2-PYRIDYL)-2,2'-4,4''-2'',2'''-QUATERPYRIDINE - BACK-TO-BACK 2,2'-6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

WARD, MD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (04) :1405-1409

[4] Pentaerythritol-based metallodendrimers [J].

Constable, EC ;

Housecroft, CE ;

Cattalini, M ;

Phillips, D .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (02) :193-200

[5] Five-component assembly of molecular loops [J].

Constable, EC ;

Phillips, D .

CHEMICAL COMMUNICATIONS, 1997, (09) :827-828

[6]

LEHN JM, 1996, COMPREHENSIVE COORDI, V9

[7] Synthesis of two covalently linked bis(2,2′:6′,2"-terpyridine) (terpy) chelating ligands with different length spacers, comparison of the crystal structures of their mononuclear nickel(II) complexes, and kinetic and mechanistic studies of the reaction of one ligand with [Fe(terpy)2]2+ [J].

Priimov, GU ;

Moore, P ;

Maritim, PK ;

Butalanyi, PK ;

Alcock, NW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (04) :445-449

[8] Monitoring the iron(II)-induced self-assembly of preorganized tritopic ligands by electrospray mass spectrometry: Unique formation of metallomacrocycles [J].

Romero, FM ;

Ziessel, R ;

DupontGervais, A ;

VanDorsselaer, A .

CHEMICAL COMMUNICATIONS, 1996, (04) :551-553

[9] A STRAIGHTFORWARD SYNTHESIS OF 5-BROMO AND 5,5'-DIBROMO-2,2'-BIPYRIDINES [J].

ROMERO, FM ;

ZIESSEL, R .

TETRAHEDRON LETTERS, 1995, 36 (36) :6471-6474

[10] 4′-functionalized 2,2′:6′,2"-terpyridines as building blocks for supramolecular chemistry and nanoscience [J].

Schubert, US ;

Eschbaumer, C ;

Hien, O ;

Andres, PR .

TETRAHEDRON LETTERS, 2001, 42 (28) :4705-4707

← 1 2 →