Orange II photocatalysis on immobilised TiO2 Effect of the pH and H2O2

被引：147

作者：

Fernández, J

Kiwi, J

Baeza, J

Freer, J

Lizama, C

Mansilla, HD

机构：

[1] Univ Concepcion, Fac Chem Sci, Lab Renewable Resources, Concepcion, Chile

[2] Ecole Polytech Fed Lausanne, IMCB, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2004年 / 48卷 / 03期

关键词：

experimental design; immobilised TiO2; orange II; photocatalysis; pH and H2O2 effect;

D O I：

10.1016/j.apcatb.2003.10.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The discoloration and mineralisation of the azo-dye Orange II in a photoreactor using TiO2-coated glass rings as immobilised photocatalyst is reported. The variation of pH and the H2O2 addition effect were systematically investigated. The use of the response surface methodology allowed to fit the optimal values of the parameters leading to Orange II abatement. Also, a single polynomial expression modelling the reaction was obtained. The photocatalytic degradation of Orange II was followed by spectrophotometric analysis and total organic carbon (TOC) measurements. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：205 / 211

页数：7

共 31 条

[1] Photochemical and heterogeneous photocatalytic degradation of waste vinylsulphone dyes: a case study with hydrolysed Reactive Black 5
Alaton, IA
Balcioglu, IA
[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 141 (2-3) : 247 - 254
[2] Advanced oxidation of synthetic dyehouse effluent by O3,H2O2/O3 and H2O2/UV processes
Arslan, I
Balcioglu, IA
Tuhkanen, T
[J]. ENVIRONMENTAL TECHNOLOGY, 1999, 20 (09) : 921 - 931
[3] Catalytic ozonation of oxalic acid in an aqueous TiO2 slurry reactor
Beltrán, FJ
Rivas, FJ
Montero-de-Espinosa, R
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 39 (03) : 221 - 231
[4] BLANCO J, 1999, Patent No. 9902508
[5] Box G.E., 1978, STAT EXPT
[6] A kinetic model for photocatalytic degradation of organic contaminants in a thin-film TiO2 catalyst
Chang, HT
Wu, NM
Zhu, FQ
[J]. WATER RESEARCH, 2000, 34 (02) : 407 - 416
[7] Photocatalytic reduction of hydrazine to ammonia catalysed by [RuIII(edta)(H2O)]- complex in a Pt/TiO2 semiconductor particulate system
Chatterjee, D
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 154 (1-2) : 1 - 3
[8] Photocatalytic degradation of 17-β-oestradiol on immobilised TiO2
Coleman, HM
Eggins, BR
Byrne, JA
Palmer, FL
King, E
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 24 (01) : L1 - L5
[9] Photocatalytic deactivation of commercial TiO2 samples during simultaneous photoreduction of Cr(VI) and photooxidation of salicylic acid
Colón, G
Hidalgo, MC
Navío, JA
[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 138 (01) : 79 - 85
[10] de Moraes SG, 2000, CHEMOSPHERE, V40, P369

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