A comparative study of diffusion profiles in Himalayan and Dalradian garnets: Constraints on diffusion data and the relative duration of the metamorphic events

Cation diffusion rates at 690 +/- 30 degrees C have been calculated by inverse modelling of observed manganese (Mn) zonation profiles in 40 garnets from two kyanite-bearing metapelite samples from the High Himalayan Crystalline Series, Zanskar. northwest India. Knowledge of the initial growth profile of Mn in garnet is a pre-requisite for this technique. Following previous workers we model Mn partitioning into growing garnet in terms of a Rayleigh fractionation process, and demonstrate that the Mn-garnet:whole rock partition coefficient is 60-100. Three-dimensional zonation profiles were obtained by successively grinding and polishing similar to 1 cm slabs of each sample at 0.1-0.2 mm intervals and analysing the garnets at each stage, thus ensuring that core sections were measured. The diffusion model assumes that garnet has a spherical geometry and behaves as a closed system, and simulates diffusive modification of the hypothetical Mn Rayleigh growth profile for each garnet. The derived measure of the time-integrated diffusion history for each garnet is then combined with radiometric and field-relation constraints for the duration of the Himalayan metamorphic event to calculate cation diffusion rates. The average cation interdiffusion rate calculated for garnets in the two samples examined is (6 +/- 3.2) x 10(-23) s(-1). This interdiffusion rate pertains to a temperature of 690 +/- 30 degrees C, which is 0.97 x T-PEAK, the peak temperature conditions experienced by the samples estimated using standard thermobarometric techniques. Garnet compositions are P(y2-17)Alm(65-77)Gro(6-16)Sp(1-17). These new diffusion data are consistent with, and more precise than, existing high-temperature (> 1000 degrees C) experimentally determined diffusion data, although some uncertainties remain difficult to constrain, Qualitative comparison between diffusively modified Mn growth profiles in garnets from the Scottish Dalradian and the Himalayan garnets suggests that the duration of metamorphism affecting the Dalradian garnets was 10-20 times longer than that endured by the Himalayan garnets.