Improvement of polyacrylate coating by filling modified nano-TiO2

被引:57
作者
Chen, Yunhua [1 ]
Lin, An [1 ]
Gan, Fuxing [1 ]
机构
[1] Wuhan Univ, Coll Resource & Environm Sci, Wuhan 430072, Peoples R China
基金
中国国家自然科学基金;
关键词
nano-TiO2; modification; polyacrylate coating; water absorption; permeability;
D O I
10.1016/j.apsusc.2005.11.083
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nano-TiO2 is modified by a method, by which nano-TiO2 first reacts with silane coupling agent WD-70 with double bond group which subsequently copolymerizes with methyl methacrylate and butyl acrylate to produce a thin polymer shell on the nanoparticles. The modified nanoparticles have stable organophilicity. They are applied to polyacrylate coating and performances of the coating are measured by different methods. The modification of nano-TiO2 particles can improve their dispersibility in coating, enhance hardness of coating and reduce water absorption and permeability of polyacrylate coating. The mechanism has been analyzed in this paper. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:8635 / 8640
页数:6
相关论文
共 16 条
[1]   Trialkoxysilane grafting onto nanoparticles for the preparation of clear coat polyacrylate systems with excellent scratch performance [J].
Bauer, F ;
Gläsel, HJ ;
Decker, U ;
Ernst, H ;
Freyer, A ;
Hartmann, E ;
Sauerland, V ;
Mehnert, R .
PROGRESS IN ORGANIC COATINGS, 2003, 47 (02) :147-153
[2]  
Bauer F, 2000, MACROMOL CHEM PHYSIC, V201, P2654, DOI 10.1002/1521-3935(20001201)201:18<2654::AID-MACP2654>3.0.CO
[3]  
2-N
[4]   Thermal stability and water uptake of high performance epoxy layered silicate nanocomposites [J].
Becker, O ;
Varley, RJ ;
Simon, GP .
EUROPEAN POLYMER JOURNAL, 2004, 40 (01) :187-195
[5]   Epoxy layered-silicate nanocomposites [J].
Chen, CG ;
Khobaib, M ;
Curliss, D .
PROGRESS IN ORGANIC COATINGS, 2003, 47 (3-4) :376-383
[6]   Crack-bridging ability and liquid water permeability of protective coatings for concrete [J].
Delucchi, M ;
Barbucci, A ;
Cerisola, G .
PROGRESS IN ORGANIC COATINGS, 1998, 33 (01) :76-82
[7]   Wettability of fine silica powder surfaces modified with several normal alcohols [J].
Fuji, M ;
Takei, T ;
Watanabe, T ;
Chikazawa, M .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 154 (1-2) :13-24
[8]   Surface-modification of SiO2 nanoparticles with oleic acid [J].
Li, ZW ;
Zhu, YF .
APPLIED SURFACE SCIENCE, 2003, 211 (1-4) :315-320
[9]   Surface modification of nano-apatite by grafting organic polymer [J].
Liu, Q ;
de Wijn, JR ;
de Groot, K ;
van Blitterswijk, CA .
BIOMATERIALS, 1998, 19 (11-12) :1067-1072
[10]   The sorption characteristics of epoxy coatings electrodeposited on steel during exposure to different corrosive agents [J].
MiskovicStankovic, VB ;
Drazic, DM ;
KacarevicPopovic, Z .
CORROSION SCIENCE, 1996, 38 (09) :1513-1523