Mercury porosimetry applied to sono-aerogels

被引:13
作者
Esquivias, L [1 ]
De La Rosa-Fox, N [1 ]
机构
[1] Univ Cadiz, Dept Fis Mat Condensada, Cadiz 11517, Spain
关键词
sonogel; aerogel; mercury intrusion; bulk modulus;
D O I
10.1023/A:1020752911418
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 [材料科学与工程]; 080502 [材料学];
摘要
Sonogels are dense with fine and homogeneous structure because the absence of a common solvent of the metalorganic precursor + water and, mainly, because the ultrasound favour network reticulation. This fact represents that the elastic modulus is several order of magnitude higher than gels obtained without ultrasound. The combination of high stiffness and tiny porosity allows actual intrusion of Hg in a porosimetry experiment. In this paper the behaviour of under isostatic pressure a number of sonogels prepared under different conditions is presented.
引用
收藏
页码:651 / 655
页数:5
相关论文
共 11 条
[1]
Blanco E, 1999, APPL ORGANOMET CHEM, V13, P399, DOI 10.1002/(SICI)1099-0739(199905)13:5<399::AID-AOC825>3.0.CO
[2]
2-A
[3]
Irreversible volume shrinkage of silica aerogels under isostatic pressure [J].
Duffours, L ;
Woignier, T ;
Phalippou, J .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 194 (03) :283-290
[4]
Structural models of dense aerogels [J].
Esquivias, L ;
Rodriguez-Ortega, J ;
Barrera-Solano, C ;
De la Rosa-Fox, N .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 225 (1-3) :239-243
[5]
METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON [J].
HORVATH, G ;
KAWAZOE, K .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) :470-475
[6]
Aerogel compression theoretical analysis [J].
Pirard, R ;
Pirard, JP .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1997, 212 (2-3) :262-267
[7]
Mercury porosimetry applied to low density xerogels; relation between structure and mechanical properties [J].
Pirard, R ;
Heinrichs, B ;
Van Cantfort, O ;
Pirard, JP .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1998, 13 (1-3) :335-339
[8]
INTERPRETATION OF MERCURY POROSIMETRY APPLIED TO AEROGELS [J].
PIRARD, R ;
BLACHER, S ;
BROUERS, F ;
PIRARD, JP .
JOURNAL OF MATERIALS RESEARCH, 1995, 10 (08) :2114-2119
[9]
COMPRESSION OF AEROGELS [J].
SCHERER, GW ;
SMITH, DM ;
QIU, XM ;
ANDERSON, JM .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 186 :316-320
[10]
CRITICAL STRESS INTENSITY FACTORS OF WET GELS [J].
ZARZYCKI, J .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 100 (1-3) :359-363