27Al field-swept and frequency-stepped NMR for sites with large quadrupole coupling constants

被引：16

作者：

Bryant, PL

Butler, LG ^{[1
]}

Reyes, AP

Kuhns, P

机构：

[1] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

[2] Natl High Magnet Field Lab, Tallahassee, FL 32306 USA

来源：

SOLID STATE NUCLEAR MAGNETIC RESONANCE | 2000年 / 16卷 / 1-2期

关键词：

field-swept NMR; frequency-stepped NMR; imidoalane; Al-27; NMR; quadrupolar coupling constant;

D O I：

10.1016/S0926-2040(00)00055-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spectra of nonspinning samples with large quadrupole coupling constants, 16-32 MHz, are acquired by frequency-stepping. A series of spin-echoes are acquired at arbitrary frequency increments, frequency-shifted in the time domain, and co-added as magnitude spectra. This procedure is derived from a method in use for field-swept NMR. The two methods are compared. (C) 2000 Elsevier Science B.V. All rights reserved.

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页码：63 / 67

页数：5

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