Chiral C2 and C1 symmetric (cyclooctane-1,5-diyl)bis(2-pyrazolyl)borate complexes of potassium and thallium.: Preparation, structures and solution behavior

被引：12

作者：

Chisholm, MH ^{[1
]}

Iyer, SS

Streib, WE

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 06期

关键词：

D O I：

10.1039/a906582b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation, structures and solution behavior of {(cyclooctane-1,5-diyl)bis[(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-indazol-2-yl]borato-kappa N-1,kappa N-1'}metal, where metal = K, 1, or Tl, 2, {(cyclooctane-1,5-diyl)[(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-indazol-2-yl][(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-indazol-2-yl]borato-kappa N-1,kappa N-1'}potassium-tetrahydrofuran(1/3), 3 . 3THF, and {(cyclooctane-1,5-diyl)bis[(4R,7R)-7-isopropyl-4-methyl-4,5,6,7-tetrahydro-2H-indazol-2-yl]borato-kappa N-1,kappa N-1'}potassium-tetrahydrofuran(1/4), 4 . 4THF, are reported.

引用

页码：393 / 398

页数：6

共 15 条

[1] SYNTHESIS AND 2D NMR-STUDIES OF (BIS(PYRAZOLYL)BORATO)RHODIUM(I) COMPLEXES WITH WEAK RH...H...C INTERACTIONS AND THE X-RAY CRYSTAL-STRUCTURE OF ((CYCLOOCTANE-1,5-DIYL)BIS(PYRAZOL-1-YL)BORATO)(1,5-CYCLOOCTADIENE)RHODIUM [J].