Why ionic liquids can possess extra solvent power

被引：33

作者：

Aerov, Artem A.

Khokhlov, Alexei R.

Potemkin, Igor I. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119992, Russia

[2] Univ Ulm, Dept Polymer Sci, D-89069 Ulm, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 33期

关键词：

D O I：

10.1021/jp062710i

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We use the Flory-Huggins theory to demonstrate conditions of extra solvent power of ionic liquids. The short-range interactions between anions, cations, and molecules of the solute are taken into account. We find that solvent power of the ionic liquids is enhanced if non-Coulomb interactions between the anions and cations are repulsive. The mechanism responsible for the extra solvent power is related to the "shielding" of the anion-cation interactions by the molecules of the solute.

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页码：16205 / 16207

页数：3

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