Toward Main Chain Metallo-Terpyridyl Supramolecular Polymers: "The Metal Does the Trick"

被引：87

作者：

Chiper, Manuela ^{[1
,2
]}

Hoogenboom, Richard ^{[1
,2
]}

Schubert, Ulrich S. ^{[1
,2
,3
]}

机构：

[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[2] Dutch Polymer Inst DPI, NL-5600 MB Eindhoven, Netherlands

[3] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2009年 / 30卷 / 08期

关键词：

metal-ligand coordination; metallo-polymerization; stimuli-responsive polymers; structure; supramolecular chemistry; terpyridines; viscosity; BUILDING-BLOCKS; COORDINATION POLYMERS; COMPLEXES; CHEMISTRY; COPOLYMERS; BIPYRIDINE; BEHAVIOR; RODLIKE; SENSORS; ROUTE;

D O I：

10.1002/marc.200800625

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Metallo-supramolecular chemistry offers possibilities for the construction of stimuli-responsive polymeric materials where the environment can have a large impact on the reversibility and strength of interactions between the individual components. The potential of manipulating the strength of the intermolecular non-covalent bonds can result in impressive modifications of the metallo-supramolecular structure and, subsequently, produces changes in the properties of the designed material. The present feature article provides an overview on recent developments in the field of metallo-polymerization of chelating terpyridyl and analogues ligands. Synthetic strategies are described followed by a discussion regarding the characterization and the application of the reviewed metallo-supramolecular structures, mainly based on terpyridines.

引用

页码：565 / 578

页数：14

共 77 条

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