Synthesis and magnetic property of a novel SWNT-poly(Schiff base)-Nd3+ complex

被引：15

作者：

He, BJ

Sun, WL ^{[1
]}

Wang, M

Shen, ZQ

机构：

[1] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China

[2] Zhejiang Univ, Dept Phys, Hangzhou 310027, Peoples R China

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2004年 / 87卷 / 01期

基金：

中国国家自然科学基金;

关键词：

bithiazole-containing polymer; magnetic properties; nanotube-based polymeric rare earth ions complex;

D O I：

10.1016/j.matchemphys.2004.05.042

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A novel complex of SWNT-PDTEN-Nd3+ was prepared though coordination action of polymer to introduce Nd3+ in SWNT-PDTEN system. The magnetic behavior of the complex was measured as a function of the magnetic field strength (0-60 kOe) at 5 K and a function of temperature (5-300 K). New magnetic phenomena of temperature dependence of magnetization for SWNT-PDTEN-Nd3+ are observed. The ferromagnetism of polymeric complex directly turns to diamagnetism at transition temperature of 125 K. It exhibits a hysteresis loop at 5 K with small coercivity (165 Oe) and remnant magnetization of 0.008 emu/g, which indicates that this complex possesses soft ferromagnetic property. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：222 / 226

页数：5

共 25 条

[1] CAPILLARITY-INDUCED FILLING OF CARBON NANOTUBES [J].