The concept of effective spheres in the theory of bimolecular processes in liquid solutions

被引：17

作者：

Doktorov, AB ^{[1
]}

Kipriyanov, AA ^{[1
]}

机构：

[1] NOVOSIBIRSK STATE UNIV,NOVOSIBIRSK 630090,RUSSIA

来源：

MOLECULAR PHYSICS | 1996年 / 88卷 / 02期

关键词：

D O I：

10.1080/00268979650026451

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A general kinetic law governing the attainment of a rate constant steady state in irreversible reactions in liquid solutions has been deduced in the case of mixing by free motion in configuration space. Based on this law, the applicability of the absorbing sphere concept for a qualitative description of irreversible reactions in liquid solutions has been analysed, and results for rate constant long-term asymptotics in the specific case of diffusion-influenced reactions has been examined.

引用

页码：453 / 464

页数：12

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