A novel light-emitting mixed-ligand iridium(III) complex with a terpyridine-poly (ethylene glycol) macroligand

被引：42

作者：

Holder, E

Marin, V

Meier, MAR

Schubert, US

机构：

[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[2] DPI, NL-5600 MB Eindhoven, Netherlands

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 16期

关键词：

end-group functionalized poly(ethylene glycol); light-emitting iridium(III) complex; luminescence; MALDI; terpyridine;

D O I：

10.1002/marc.200400206

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A monoterpyridine-poly(ethylene glycol) (monotpy-PEG) and a novel monoterpyridine-PEG-functionalized iridium(III) complex were successfully synthesized and fully characterized by means of NMR, IR, and UV-vis spectroscopy, as well as gel permeation chromatography and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. The functionalized monoterpyridine I iridium(III) complex was synthesized by a bridge-splitting reaction of a dimeric iridium(III) precursor complex using a chelating terpyridine ligand with a poly(ethylene glycol) tail. With this approach, a new class of light-emitting polymeric materials revealing interesting optical properties was made avaialable.

引用

页码：1491 / 1496

页数：6

共 22 条

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[2]

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