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Dissolved oxygen sensor based on fluorescence quenching of oxygen-sensitive ruthenium complex immobilized on silica-Ni-P composite coating
被引:37
作者:
Xiong, Xiaoli
Xiao, Dan
[1
]
Choi, Martin. M. F.
机构:
[1] Sichuan Univ, Coll Chem Engn, Chengdu 610065, Peoples R China
[2] SW Univ Sci & Technol, Dept Mat Sci & Engn, Mianyang 621002, Peoples R China
[3] Hong Kong Baptist Univ, Dept Chem, Hong Kong, Hong Kong, Peoples R China
关键词:
dissolved oxygen sensor;
fluorescence quenching;
silica-Ni-P composite coating;
D O I:
10.1016/j.snb.2005.11.044
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
A dissolved oxygen sensor based on the dynamic quenching of fluorescence from a ruthenium complex immobilized in a silica-Ni-P composite coating is reported. The silica-Ni-P composite coating was fabricated by dip-coating onto a 200 mesh copper-screen substrate. The composite coating was then doped with an oxygen-sensitive ruthenium complex, tris(2,2'-bipyridine)ruthenium dichloride, the fluorescence of which is quenched in the presence of oxygen. The preliminary result obtained with this composite coating indicates that this method can be an alternative approach for immobilizing oxygen-sensitive luminescent reagents. (c) 2005 Elsevier B.V. All rights reserved.
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页码:172 / 176
页数:5
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