Superparamagnetic behavior of nanosized Co0.2Zn0.8Fe2O4 synthesized by a flow rate controlled chemical coprecipitation method

We have studied the structural, microstructural and magnetic properties of nanosized (similar to 20 nm) Co0.2Zn0.8Fe2O4 synthesized by a flow rate controlled coprecipitation method. The phase purity and crystallinity of the sample have been confirmed by powder X-ray diffraction and high resolution transmission electron microscopic studies. According to the results of dc magnetic measurements the sample exhibits superparamagnetic behavior above 70 K due to its nanometric size. This has been corroborated by Mossbauer spectroscopic study at 300 K. The infield Mossbauer spectroscopic study indicates that the sample behaves ferrimagnetically at 10 K and it possesses equilibrium cation distribution. The saturation magnetization of the sample (M-SAT similar to 32 emu g(-1) at 300 K) is substantially lower than its bulk counterpart (M-SAT = 80 emu g(-1)) but higher than those having same composition synthesized by the conventional coprecipitation method. This has been attributed to finite size and spin canting effects as well as good crystalline character and bulk like equilibrium cation distribution of the sample. We have shown that the flow rate controlled coprecipitation method can produce nanosized ferrites with very good crystalline order and equilibrium cation distribution but they exhibit reduction of magnetization, magnetic order and ordering temperature compared to their bulk counterparts due to spin canting effect and finite size effect. (C) 2014 Elsevier B.V. All rights reserved,