Calculation of rotationally inelastic processes in electron collisions with CO2 molecules

被引:6
作者
Gianturco, FA
Stoecklin, T
机构
[1] MAX PLANCK INST STROMUNGSFORSCH, D-37173 GOTTINGEN, GERMANY
[2] LAB PHYSICOCHIM THEOR, F-33400 TALENCE, FRANCE
来源
PHYSICAL REVIEW A | 1997年 / 55卷 / 03期
关键词
D O I
10.1103/PhysRevA.55.1937
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The rotational excitation of the title linear polyatomic target, treated as a rigid rotor is computed using a fully ab initio interaction potential recently employed to obtain integral elastic cross sections [Gianturco and Stoecklin, J. Phys. B 29, 3933 (1996)] and to unravel several resonances in the low-energy region. The present study looks at the rotationally inelastic processes which can occur in the energy range across the ling-lived shape resonance at 3.9 eV and finds that the resonant process strongly enhances the overall efficiency of the rotational excitation by the electron projectile, as shown by the computed values of the average rotational energy transfers. Angular distributions are also evaluated at different collision energies and compared with earlier calculations.
引用
收藏
页码:1937 / 1944
页数:8
相关论文
共 28 条
[1]   ANGULAR DISTRIBUTIONS FOR EXCITATION OF VIBRONIC STATES BY RESONANT ELECTRON MOLECULE REACTIONS [J].
ANDRICK, D ;
READ, FH .
JOURNAL OF PHYSICS PART B ATOMIC AND MOLECULAR PHYSICS, 1971, 4 (03) :389-&
[2]   THE THEORY OF SCATTERING BY A RIGID ROTATOR [J].
ARTHURS, AM ;
DALGARNO, A .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1960, 256 (1287) :540-551
[3]   EXCITATION OF 4.3-MUM BANDS OF CO2 BY LOW-ENERGY ELECTRONS [J].
BULOS, BR ;
PHELPS, AV .
PHYSICAL REVIEW A, 1976, 14 (02) :615-629
[4]   RELATIONSHIP BETWEEN ADIABATIC-NUCLEI AND FRAME-TRANSFORMATION THEORIES OF E(-)-MOLECULE SCATTERING [J].
CHANDRA, N .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1975, 8 (11) :1953-1958
[5]   ADIABATIC APPROXIMATION FOR SCATTERING PROCESSES [J].
CHASE, DM .
PHYSICAL REVIEW, 1956, 104 (03) :838-842
[6]   ROTATIONAL EXCITATION AND MOMENTUM TRANSFER CROSS SECTIONS FOR ELECTRONS IN H2 AND N2 FROM TRANSPORT COEFFICIENTS [J].
FROST, LS ;
PHELPS, AV .
PHYSICAL REVIEW, 1962, 127 (05) :1621-&
[7]  
Gianturco F. A., 1979, TRANSFER MOL ENERGY
[8]   The elastic scattering of electrons from CO2 molecules .1. Close coupling calculations of integral and differential cross sections [J].
Gianturco, FA ;
Stoecklin, T .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1996, 29 (17) :3933-3954
[9]   ELECTRON-SCATTERING FROM ACETYLENE - ELASTIC INTEGRAL AND DIFFERENTIAL CROSS-SECTIONS AT LOW ENERGIES [J].
GIANTURCO, FA ;
STOECKLIN, T .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1994, 27 (24) :5903-5921
[10]  
Gianturco FA, 1996, MOL PHYS, V89, P753, DOI 10.1080/00268979609482505