Insights into few-layer epitaxial graphene growth on 4H-SiC(000(1)over-bar substrates from STM studies

被引:198
作者
Biedermann, Laura B. [1 ,2 ]
Bolen, Michael L. [2 ,3 ]
Capano, Michael A. [2 ,3 ]
Zemlyanov, Dmitry [2 ]
Reifenberger, Ronald G. [1 ,2 ]
机构
[1] Purdue Univ, Dept Phys, W Lafayette, IN 47907 USA
[2] Purdue Univ, Birck Nanotechnol Ctr, W Lafayette, IN 47907 USA
[3] Purdue Univ, Sch Elect Engn, W Lafayette, IN 47907 USA
来源
PHYSICAL REVIEW B | 2009年 / 79卷 / 12期
关键词
SCANNING-TUNNELING-MICROSCOPY; CHEMICAL-VAPOR-DEPOSITION; THIN GRAPHITE FILMS; SILICON-CARBIDE; ATOMIC-STRUCTURE; SURFACE; 6H-SIC(0001); GRAPHITIZATION; IMAGES; SCATTERING;
D O I
10.1103/PhysRevB.79.125411
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
Epitaxial carbon was grown by heating (000 (1) over bar) silicon carbide (SiC) to high temperatures (1450-1600 degrees C) in vacuum. A continuous graphene surface layer was formed at temperatures above 1475 degrees C. X-ray photo-electron spectroscopy (XPS) and scanning tunneling microscopy (STM) were extensively used to characterize the quality of the few-layer graphene (FLG) surface. The XPS studies were useful in confirming the graphitic composition and measuring the thickness of the FLG samples. STM studies revealed a wide variety of nanometer-scale features that include sharp carbon-rich ridges, moire superlattices, one-dimensional line defects, and grain boundaries. By imaging these features with atomic-scale resolution, considerable insight into the growth mechanisms of FLG on the carbon face of SiC is obtained.
引用
收藏
页数:10
相关论文
共 64 条
[1]
Graphitization of the 6H-SiC(0001) surface studied by HREELS [J].
Angot, T ;
Portail, M ;
Forbeaux, I ;
Layet, JM .
SURFACE SCIENCE, 2002, 502 :81-85
[2]
TOPOGRAPHICAL CHANGES INDUCED BY HIGH-DOSE CARBON-BOMBARDMENT OF GRAPHITE [J].
ANNIS, BK ;
PEDRAZA, DF ;
WITHROW, SP .
JOURNAL OF MATERIALS RESEARCH, 1993, 8 (10) :2587-2599
[3]
Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[4]
Monolayers of graphite rotated by a defined angle:: hexagonal superstructures by STM [J].
Beyer, H ;
Müller, M ;
Schimmel, T .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1999, 68 (02) :163-166
[5]
Scanning tunneling spectroscopy of inhomogeneous electronic structure in monolayer and bilayer graphene on SiC [J].
Brar, Victor W. ;
Zhang, Yuanbo ;
Yayon, Yossi ;
Ohta, Taisuke ;
McChesney, Jessica L. ;
Bostwick, Aaron ;
Rotenberg, Eli ;
Horn, Karsten ;
Crommie, Michael F. .
APPLIED PHYSICS LETTERS, 2007, 91 (12)
[6]
Exchange-induced charge inhomogeneities in rippled neutral graphene [J].
Brey, L. ;
Palacios, J. J. .
PHYSICAL REVIEW B, 2008, 77 (04)
[7]
Density functional calculations on the intricacies of Moire patterns on graphite [J].
Campanera, J. M. ;
Savini, G. ;
Suarez-Martinez, I. ;
Heggie, M. I. .
PHYSICAL REVIEW B, 2007, 75 (23)
[8]
Buckle or break [J].
Carlsson, Johan M. .
NATURE MATERIALS, 2007, 6 (11) :801-802
[9]
The role of defects on the electronic structure of a graphite surface [J].
Cervenka, J. ;
Flipse, C. F. J. .
PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON NANOSCIENCE AND TECHNOLOGY, 2007, 61 :190-194
[10]
Solid-state decomposition of silicon carbide for growing ultra-thin heteroepitaxial graphite films [J].
Charrier, A ;
Coati, A ;
Argunova, T ;
Thibaudau, F ;
Garreau, Y ;
Pinchaux, R ;
Forbeaux, I ;
Debever, JM ;
Sauvage-Simkin, M ;
Themlin, JM .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (05) :2479-2484