Unusual adsorption mechanism for carboxylic acid gases by polyamine-intercalated α-zirconium phosphate

被引：25

作者：

Nakayama, H ^{[1
]}

Hayashi, A

Eguchi, T

Nakamura, N

Tsuhako, M

机构：

[1] Kobe Pharmaceut Univ, Dept Funct Mol Chem, Kobe, Hyogo 6588558, Japan

[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 10期

关键词：

D O I：

10.1039/b201295m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption mechanism of gaseous carboxylic acid by diethylenetriamine- or pentaethylenehexamine-intercalated alpha-zirconium phosphate was examined in detail using XRD and solid-state C-13 and P-31 NMR. The adsorption of acetic acid, propanoic acid, and butyric acid resulted in the co-intercalation of the carboxylic acid molecules into polyamine-intercalated alpha-zirconium phosphate to expand their interlayer distance by 0.64-0.97 nm. In the case of formic acid, its adsorption induced the rearrangement of the polyamine molecules within the interlayer space.

引用

页码：3093 / 3099

页数：7

共 18 条

[1] SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPIC STUDY OF GAMMA-ZIRCONIUM PHOSPHATE [J].

CLAYDEN, NJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (08) :1877-1881

[2] NEW CRYSTALLINE PHASES OF ZIRCONIUM PHOSPHATE POSSESSING ION-EXCHANGE PROPERTIES [J].

CLEARFIELD, A ;

BLESSING, RH ;

STYNES, JA .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (08) :2249-+

[3] THE PREPARATION OF CRYSTALLINE ZIRCONIUM PHOSPHATE AND SOME OBSERVATIONS ON ITS ION EXCHANGE BEHAVIOUR [J].

CLEARFIELD, A ;

STYNES, JA .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1964, 26 (01) :117-129

[4]

Clearfield A., 1996, COMPREHENSIVE SUPRAM, V7, P107

[5] Intercalation of methylene blue into layered phosphates in the presence of butylamine and function of alkylamine in the intercalation reaction [J].

Danjo, M ;

Tsuhako, M ;

Nakayama, H ;

Eguchi, T ;

Nakamura, N ;

Yamaguchi, S ;

Nariai, H ;

Motookata, I .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (05) :1053-1060

[6] Structure and organic gas-adsorption properties of some polyamine intercalated α-zirconium phosphates [J].

Danjo, M ;

Hayashi, A ;

Nakayama, H ;

Kimira, Y ;

Shimizu, T ;

Mizuguchi, Y ;

Yagita, Y ;

Tsuhako, M ;

Nariai, H ;

Motooka, I .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (09) :2079-2084

[7] PYRENE SORPTION IN ORGANIC LAYERED DOUBLE-METAL HYDROXIDES [J].

DUTTA, PK ;

ROBINS, DS .

LANGMUIR, 1994, 10 (06) :1851-1856

[8] Intercalation of α,ω-alkanediamines in layered aluminium dihydrogen triphosphate dihydrate [J].

Hayashi, A ;

Nakayama, H ;

Tsuhako, M ;

Eguchi, T ;

Nakamura, N .

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 1999, 34 (04) :401-412

[9]

Hayashi A, 2000, MOL CRYST LIQ CRYST, V341, P1377

[10] An acentric arrangement of p-nitroaniline molecules between the layers of kaolinite [J].

Kuroda, K ;

Hiraguri, K ;

Komori, Y ;

Sugahara, Y ;

Mouri, H ;

Uesu, Y .

CHEMICAL COMMUNICATIONS, 1999, (22) :2253-2254

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