Construction of a functional layered solid using the tetrakis(imidazolyl)borate coordinating anion

被引：31

作者：

Hamilton, BH ^{[1
]}

Kelly, KA ^{[1
]}

Wagler, TA ^{[1
]}

Espe, MP ^{[1
]}

Ziegler, CJ ^{[1
]}

机构：

[1] Univ Akron, Dept Chem, Knight Chem Lab, Akron, OH 44325 USA

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 20期

关键词：

D O I：

10.1021/ic025796c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination polymer Pb[B(Im)(4)](NO3), constructed by using tetrakis(imidazolyl)borate and lead(II) nitrate solutions, is a layered material with the metal centers facing the interlayer spacing. As occurring layered minerals, this compound can readily undergo anion exchange in the solid state with retention of crystallinity. We examined stoichiometric exchange of N-15-nitrate for nitrate and iodine for nitrate by N-15 and Pb-207 SSNMR and confirmed retention of crystallinity by IR and powder XRD diffraction.

引用

页码：4984 / 4986

页数：3

共 28 条

[1] Tailored porous materials [J].

Barton, TJ ;

Bull, LM ;

Klemperer, WG ;

Loy, DA ;

McEnaney, B ;

Misono, M ;

Monson, PA ;

Pez, G ;

Scherer, GW ;

Vartuli, JC ;

Yaghi, OM .

CHEMISTRY OF MATERIALS, 1999, 11 (10) :2633-2656

[2] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[3]

Buston JEH, 2001, MAGN RESON CHEM, V39, P68, DOI 10.1002/1097-458X(200102)39:2<68::AID-MRC802>3.0.CO

[4]

2-C

[5]

CHEETAM AK, 1992, SOLID STATE CHEM

[6] Correlation and relativistic effects in β-PbO and other lead (II) oxides:: A quantum ab initio explanation of 207Pb NMR and XANES spectra [J].

Dybowski, C ;

Gabuda, SP ;

Kozlova, SG ;

Neue, G ;

Perry, DL ;

Terskikh, VV .

JOURNAL OF SOLID STATE CHEMISTRY, 2001, 157 (01) :220-224

[7] 207Pb NMR chemical-shift tensors of the lead (II) halides and the lead (II) hydroxyhalides [J].

Dybowski, C ;

Smith, ML ;

Hepp, MA ;

Gaffney, EJ ;

Neue, G ;

Perry, DL .

APPLIED SPECTROSCOPY, 1998, 52 (03) :426-429

[8]

ENGLEHARDT LM, 1989, J CHEM SOC DA, P595

[9] Empirical correlations between Pb-207 NMR chemical shifts and structure in solids [J].

Fayon, F ;

Farnan, I ;

Bessada, C ;

Coutures, J ;

Massiot, D ;

Coutures, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (29) :6837-6843

[10] 207Pb NMR study of novel Pb-Pb chemical bonding in lead monoxides, α-PbO and β-PbO [J].

Gabuda, SP ;

Kozlova, SG ;

Terskikh, VV ;

Dybowski, C ;

Neue, G ;

Perry, DL .

CHEMICAL PHYSICS LETTERS, 1999, 305 (5-6) :353-358

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