The first metal chelation by a neutral porphyrin analogue

被引：42

作者：

Gross, Z

Saltsman, I

Pandian, RP

Barzilay, CM

机构：

[1] Department of Chemistry, Technion - Israel Inst. of Technol.

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(97)00357-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation and spectroscopic characterization of O2TTP- a modified porphyrin in which the two NH groups are replaced by oxygen atoms- and its dihalonickel(II) complexes lead to the conclusion that 21,23-dioxaporphyrins are exceptionally well suited for metal complexation and for stabilization of divalent nickel in paramagnetic pseudo-octahedral geometries. (C) 1997 Elsevier Science Ltd.

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页码：2383 / 2386

页数：4

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