Asymmetric oxidopyrylium-alkene[5+2] cycloaddition: a divergent approach for the synthesis of enantiopure oxabicyclo[5.4.0]undecanes

被引：27

作者：

Krishna, UM ^{[1
]}

Deodhar, KD ^{[1
]}

Trivedi, GK ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

TETRAHEDRON | 2004年 / 60卷 / 22期

关键词：

D-ribose; 3-oxidopyrylium; asymmetric synthesis; 5+2] cycloaddition;

D O I：

10.1016/j.tet.2004.04.003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Chiron approach to the synthesis of enantiomeric oxabicyclic adducts 16 and 32 has been developed employing an intramolecular [5+2] cycloaddition of 3-oxidopyrylium with unsaturated sugars. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：4829 / 4836

页数：8

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