学术探索
学术期刊
新闻热点
数据分析
智能评审

Charge-discharge characteristics of LiCoO2/mesocarbon microbeads battery with poly(vinyl chloride)-based composite polymer electrolyte

被引：15
作者：
Subban, RHY
Arof, AK [1 ]
机构：
[1] Univ Malaya, Fac Sci, Dept Phys, Kuala Lumpur 50603, Malaysia
[2] Univ Teknol MARA, Fac Sci Appl, Shah Alam 40500, Selangor, Malaysia
来源：
JOURNAL OF POWER SOURCES | 2004年 / 134卷 / 02期
关键词：
poly(vinyl chloride); composite polymer electrolyte; ionic conductivity; lithium battery;
D O I：
10.1016/j.jpowsour.2004.03.048
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Polyvinyl chloride (PVC)-based composite polymer electrolyte films consisting of PVC-LiCF3SO3-SiO2 are prepared by the solution-casting method. The electrical properties of the electrolyte are investigated for ionic conductivity and its dependence on temperature. The electrolyte with the highest ionic conductivity is used to fabricate a LiCoO2/PVC-LiCF3SO3-SiO2/mesocarbon microbeads (MCMB) battery. The charge-discharge characteristics and performance of the battery at room temperature are evaluated to ascertain the effective viability, of these solid electrolytes in lithium-polymer batteries. Battery performances is also investigated at 313, 323 and 333 K. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：211 / 221
页数：11
相关论文
共 33 条
[1]   ROOM-TEMPERATURE POLYMER ELECTROLYTES AND BATTERIES BASED ON THEM [J].
ABRAHAM, KM ;
ALAMGIR, M .
SOLID STATE IONICS, 1994, 70 :20-26
[2]   ROOM-TEMPERATURE RECHARGEABLE POLYMER ELECTROLYTE BATTERIES [J].
ALAMGIR, M ;
ABRAHAM, KM .
JOURNAL OF POWER SOURCES, 1995, 54 (01) :40-45
[3]  
Armand M. B., 1979, FAST ION TRANSPORT S
[4]   Preparation and electrochemical properties of glass-polymer composite electrolytes for lithium batteries [J].
Cho, JP ;
Liu, ML .
ELECTROCHIMICA ACTA, 1997, 42 (10) :1481-1488
[5]   New polymer electrolytes based on PVC/PMMA blend for plastic lithium-ion batteries [J].
Choi, NS ;
Park, JK .
ELECTROCHIMICA ACTA, 2001, 46 (10-11) :1453-1459
[6]  
DAHN J, 2000, P POW 2000 C SAN DIE
[7]   Influence of processing on the Li:Mn ratio in spinel phases of the system Li1+xMn2-xO4-delta [J].
Endres, P ;
Fuchs, B ;
KemmlerSack, S ;
Brandt, K ;
FaustBecker, G ;
Praas, HW .
SOLID STATE IONICS, 1996, 89 (3-4) :221-231
[8]   PEO based polymer electrolyte lithium-ion battery [J].
Fiory, FS ;
Croce, F ;
D'Epifanio, A ;
Licoccia, S ;
Scrosati, B ;
Traversa, E .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2004, 24 (06) :1385-1387
[9]   New lithium-ion polymer battery concept for increased capacity [J].
Hikmet, RAM .
JOURNAL OF POWER SOURCES, 2001, 92 (1-2) :212-220
[10]   Discharge-charge characteristics and performance of Li/FeOOH(an) battery with PAN-based polymer electrolyte [J].
Hwang, KS ;
Yoon, TH ;
Lee, CW ;
Son, YS ;
Hwang, JK .
JOURNAL OF POWER SOURCES, 1998, 75 (01) :13-18
1234