Comparative decoloration study of Neutral Red by different oxidative processes

被引：60

作者：

Alnuaimi, Maitha M. ^{[1
]}

Rauf, M. A. ^{[1
]}

Ashraf, S. Salman ^{[1
]}

机构：

[1] United Arab Emirates Univ, Dept Chem, Al Ain, U Arab Emirates

来源：

DYES AND PIGMENTS | 2007年 / 72卷 / 03期

关键词：

Neutral Red; comparative decoloration; Fenton's reagent; hydrogen peroxide;

D O I：

10.1016/j.dyepig.2005.09.020

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Neutral Red was subjected to two different oxidative processes, namely the photo-oxidative process and the Fenton process. The dye was found to undergo substantial and rapid decoloration by both the methods. Conditions were optimized in both the sets of experiments to achieve the most efficient dye decoloration. Additionally the effects of added anions on dye decoloration were examined and it was found that in both cases, the chloride ions caused a significant decrease in the decoloration rate. The kinetics data in both the cases fitted well to the first-order equation. A comparison of the effects of various anions on the decoloration rate revealed dramatic differences in apparent rate constant of decoloration of the dye especially in the presence of phosphate ions. Additionally the Fenton process was found to be more efficient in decolorizing the dye as compared to the photo-oxidative process. (c) 2005 Published by Elsevier Ltd.

引用

页码：367 / 371

页数：5

共 16 条

[1] ECOTOXICOLOGY OF DYESTUFFS - JOINT EFFORT BY INDUSTRY [J].

ANLIKER, R .

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 1979, 3 (01) :59-74

[2] Evaluation of predominant reaction mechanisms for the Fenton process in textile dyeing wastewater treatment [J].

Bae, W ;

Lee, SH ;

Ko, GB .

WATER SCIENCE AND TECHNOLOGY, 2004, 49 (04) :91-96

[3] Photodestruction of Acid Orange 7 (AO7) in aqueous solutions by UV/H2O2:: influence of operational parameters [J].

Behnajady, MA ;

Modirshahla, N ;

Shokri, M .

CHEMOSPHERE, 2004, 55 (01) :129-134

[4] Growth and mineral accumulation in Eucalyptus camaldulensis seedlings irrigated with mixed industrial effluents [J].

Bhati, M ;

Singh, G .

BIORESOURCE TECHNOLOGY, 2003, 88 (03) :221-228

[5]

BOENINGER M, 1980, PUBLICATION DHHS

[6]

Dai S.G., 1995, ENVIRON CHEM, V14, P354

[7] Pre-oxidation and coagulation of textile wastewater by the Fenton process [J].

Kang, SF ;

Liao, CH ;

Chen, MC .

CHEMOSPHERE, 2002, 46 (06) :923-928

[8] PHOTOCHEMICAL PROCESSES FOR WATER-TREATMENT [J].

LEGRINI, O ;

OLIVEROS, E ;

BRAUN, AM .

CHEMICAL REVIEWS, 1993, 93 (02) :671-698

[9] Environmental photochemistry:: Quantitative adsorption and FTIR studies during the TiO2-photocatalyzed degradation of Orange II [J].

Lucarelli, L ;

Nadtochenko, V ;

Kiwi, J .

LANGMUIR, 2000, 16 (03) :1102-1108

[10] Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst [J].

Malik, PK ;

Saha, SK .

SEPARATION AND PURIFICATION TECHNOLOGY, 2003, 31 (03) :241-250

← 1 2 →