Kinetics and mechanisms of polyethyleneglycol fragmentation by ozone in aqueous solution

被引：21

作者：

Andreozzi, R ^{[1
]}

Caprio, V ^{[1
]}

Insola, A ^{[1
]}

机构：

[1] UNIV NAPLES,DIPARTIMENTO INGN CHIM,I-80125 NAPLES,ITALY

来源：

WATER RESEARCH | 1996年 / 30卷 / 12期

关键词：

polyethyleneglycol; ozone; fragmentation; kinetics; mechanisms;

D O I：

10.1016/S0043-1354(96)00200-X

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The oxidative fragmentation of Polyethyleneglycol by ozone is investigated by means of batch and semibatch ozonation experiments in the pH range 4.0-9.0. Chemical mechanisms and reaction kinetics of the ozonation processes are determined by also exploiting chemical information from experiments on Diethyleneglycol and Ethyleneglycol ozonation. A kinetic model is proposed capable of describing the fragmentation process due to the direct polymer oxidation by ozone. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2955 / 2960

页数：6

共 6 条

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