Polymers interacting with mesoscopic particles

被引:19
作者
Eisenriegler, E [1 ]
机构
[1] Forschungszentrum Julich, Inst Festkorperforsch, D-52425 Julich, Germany
关键词
D O I
10.1088/0953-8984/12/8A/328
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We consider the depletion interaction between mesoscopic particles and non-adsorbing free polymer chains. For one and two spherical particles we investigate the depletion profiles of monomer and end densities of the embedding polymer solution. The profiles take a finite limit for large Flory radius and Edwards screening length. The influence of the excluded volume interaction between chain monomers is studied for the case of one particle. We demonstrate how the polymer-induced force between two particles emerges from the monomer density profile near the surface of one of the particles. The evaluation of the polymer densities follows from a new type of 'fusion procedure' in the equivalent held theory.
引用
收藏
页码:A227 / A232
页数:6
相关论文
共 19 条
[1]   INTERACTION BETWEEN PARTICLES SUSPENDED IN SOLUTIONS OF MACROMOLECULES [J].
ASAKURA, S ;
OOSAWA, F .
JOURNAL OF POLYMER SCIENCE, 1958, 33 (126) :183-192
[2]  
Asakura S., 1954, J CHEM PHYS, V22, P155
[3]   Polymer depletion interaction between a particle and a wall [J].
Bringer, A ;
Eisenriegler, E ;
Schlesener, F ;
Hanke, A .
EUROPEAN PHYSICAL JOURNAL B, 1999, 11 (01) :101-119
[4]   CASIMIR INTERACTION OF SPHERES IN A FLUID AT THE CRITICAL-POINT [J].
BURKHARDT, TW ;
EISENRIEGLER, E .
PHYSICAL REVIEW LETTERS, 1995, 74 (16) :3189-3192
[5]   CONFORMAL THEORY OF ENERGY CORRELATIONS IN THE SEMI-INFINITE TWO-DIMENSIONAL O(N) MODEL [J].
BURKHARDT, TW ;
EISENRIEGLER, E ;
GUIM, I .
NUCLEAR PHYSICS B, 1989, 316 (03) :559-572
[6]   CONFORMAL THEORY OF THE 2-DIMENSIONAL O(N) MODEL WITH ORDINARY, EXTRAORDINARY, AND SPECIAL BOUNDARY-CONDITIONS [J].
BURKHARDT, TW ;
EISENRIEGLER, E .
NUCLEAR PHYSICS B, 1994, 424 (03) :487-504
[7]  
de Gennes P.G., 1979, SCALING CONCEPTS POL
[8]  
DEGENNES PG, 1979, CR ACAD SCI B PHYS, V288, P359
[9]   CASIMIR FORCES BETWEEN SPHERICAL-PARTICLES IN A CRITICAL FLUID AND CONFORMAL-INVARIANCE [J].
EISENRIEGLER, E ;
RITSCHEL, U .
PHYSICAL REVIEW B, 1995, 51 (19) :13717-13734
[10]   Polymers interacting with spherical and rodlike particles [J].
Eisenriegler, E ;
Hanke, A ;
Dietrich, S .
PHYSICAL REVIEW E, 1996, 54 (02) :1134-1152