Phase behaviour of room temperature ionic liquid solutions: an unusually large co-solvent effect in (water plus ethanol)

被引：222

作者：

Najdanovic-Visak, V

Esperanca, JMSS

Rebelo, LPN

da Ponte, MN

Guedes, HJR

Seddon, KR

Szydlowski, J

机构：

[1] Univ Nova Lisboa, Inst Tecnol Quim & Biol, P-2780901 Oeiras, Portugal

[2] Univ Nova Lisboa, FCT, Dept Quim, REQUIMTE CQFB, P-2829516 Caparica, Portugal

[3] Queens Univ Belfast, QUILL Ctr, Belfast BT9 5AG, Antrim, North Ireland

[4] Univ Warsaw, Dept Chem, PL-02089 Warsaw, Poland

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2002年 / 4卷 / 10期

关键词：

D O I：

10.1039/b201723g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6] + (water + ethanol)). For a molar ratio of 1:1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.

引用

页码：1701 / 1703

页数：3

共 22 条

[1] Solution thermodynamics of imidazolium-based ionic liquids and water [J].