Electronic structure of Si(111)-bound alkyl monolayers: Theory and experiment

被引：102

作者：

Segev, Lior

Salomon, Adi

Natan, Amir

Cahen, David

Kronik, Leeor ^{[1
]}

Amy, Fabrice

Chan, Calvin K.

Kahn, Antoine

机构：

[1] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel

[2] Princeton Univ, Dept Elect Engn, Princeton, NJ 08540 USA

来源：

PHYSICAL REVIEW B | 2006年 / 74卷 / 16期

关键词：

D O I：

10.1103/PhysRevB.74.165323

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We elucidate the electronic structure of both filled and empty states of ordered alkyl chains bound to the Si(111) surface by combining direct and inverse photoemission spectroscopy with first principles calculations based on density functional theory. We identify both filled and empty interface-induced gap states, distinguish between those and states extending throughout the monolayer, and discuss the importance of these findings for interpreting transport experiments through such monolayers.

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页数：6

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