The synthesis of hybrid polymers using atom transfer radical polymerization: Homopolymers and block copolymers from polyhedral oligomeric silsesquioxane monomers

被引：196

作者：

Pyun, J ^{[1
]}

Matyjaszewski, K ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA

来源：

MACROMOLECULES | 2000年 / 33卷 / 01期

关键词：

D O I：

10.1021/ma9910787

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The use of atom transfer radical polymerization (ATRP) of methacrylate functional polyhedral oligomeric silsesquioxanes (POSS) monomers is described to synthesize hybrid homopolymers and block copolymers. From this approach, homopolymers, triblock copolymers, and star-block copolymers containing POSS was prepared. While polymers containing POSS were made by other methods, using ATRP, hybrid-POSS polymers with previously unattainable compositions and drastically lower polydispersities were synthesized.

引用

页码：217 / 220

页数：4

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