ENDOR and ESEEM study of the radical obtained by gamma irradiation of a single crystal of ammonium tartrate

被引:18
作者
Brustolon, M [1 ]
Maniero, AL [1 ]
Jovine, S [1 ]
Segre, U [1 ]
机构
[1] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY
关键词
D O I
10.1163/156856796X00052
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The radical obtained by gamma irradiation of a single crystal of ammonium tartrate has been identified by paramagnetic resonance spectroscopies. The proton hyperfine coupling tensors have been obtained from the angular dependence of the ENDOR transition frequencies. ESEEM spectra of the radical have been also obtained. The intensities of the ESEEM lines are related to the depth of the modulation, which has a dramatic angular dependence.
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页码:359 / 368
页数:10
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