Raman active phonons of identified semiconducting single-walled carbon nanotubes

被引:72
作者
Paillet, M. [1 ]
Michel, T.
Meyer, J. C.
Popov, V. N.
Henrard, L.
Roth, S.
Sauvajol, J. -L.
机构
[1] Univ Montpellier 2, UMR 5587, CNRS, Lab Colloides Verres & Nanomat, F-34095 Montpellier 5, France
[2] Max Planck Inst Solid State Res, Stuttgart, Germany
[3] Fac Univ Notre Dame Paix, Lab Phys Solide, B-5000 Namur, Belgium
关键词
D O I
10.1103/PhysRevLett.96.257401
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The resonant Raman spectra of (n,m) semiconducting single-walled carbon nanotubes, unambiguously identified from their electron diffraction patterns, have been measured. The diameter dependence of the frequency of the tangential modes with A symmetry has been obtained in the diameter range from 1.4 to 2.5 nm. The comparison between the excitation energies and the calculated transition energies allowed us to determine precisely the values of the E-33(s) and E-44(s) transition energies. Finally, in the debate concerning the dominant process at the origin of the first-order Raman scattering in single-walled carbon nanotubes (single resonance process or double resonance process), our results are well understood in the framework of a single resonance process.
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页数:4
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共 17 条
[1]   Measuring the uniaxial strain of individual single-wall carbon nanotubes:: Resonance Raman spectra of atomic-force-microscope modified single-wall nanotubes -: art. no. 167401 [J].
Cronin, SB ;
Swan, AK ;
Unlü, MS ;
Goldberg, BB ;
Dresselhaus, MS ;
Tinkham, M .
PHYSICAL REVIEW LETTERS, 2004, 93 (16) :167401-1
[2]   Phonons in carbon nanotubes [J].
Dresselhaus, MS ;
Eklund, PC .
ADVANCES IN PHYSICS, 2000, 49 (06) :705-814
[3]   Phonon softening in metallic nanotubes by a Peierls-like mechanism [J].
Dubay, O ;
Kresse, G ;
Kuzmany, H .
PHYSICAL REVIEW LETTERS, 2002, 88 (23) :4
[4]   Optical transition energies for carbon nanotubes from resonant Raman spectroscopy: Environment and temperature effects [J].
Fantini, C ;
Jorio, A ;
Souza, M ;
Strano, MS ;
Dresselhaus, MS ;
Pimenta, MA .
PHYSICAL REVIEW LETTERS, 2004, 93 (14) :147406-1
[5]   Resonance Raman spectroscopy (n,m)-dependent effects in small-diameter single-wall carbon nanotubes -: art. no. 075401 [J].
Jorio, A ;
Fantini, C ;
Pimenta, MA ;
Capaz, RB ;
Samsonidze, GG ;
Dresselhaus, G ;
Dresselhaus, MS ;
Jiang, J ;
Kobayashi, N ;
Grüneis, A ;
Saito, R .
PHYSICAL REVIEW B, 2005, 71 (07)
[6]   Resonance Raman spectra of carbon nanotubes by cross-polarized light -: art. no. 107403 [J].
Jorio, A ;
Pimenta, MA ;
Souza, AG ;
Samsonidze, GG ;
Swan, AK ;
Ünlü, MS ;
Goldberg, BB ;
Saito, R ;
Dresselhaus, G ;
Dresselhaus, MS .
PHYSICAL REVIEW LETTERS, 2003, 90 (10) :4
[7]   Structural (n, m) determination of isolated single-wall carbon nanotubes by resonant Raman scattering [J].
Jorio, A ;
Saito, R ;
Hafner, JH ;
Lieber, CM ;
Hunter, M ;
McClure, T ;
Dresselhaus, G ;
Dresselhaus, MS .
PHYSICAL REVIEW LETTERS, 2001, 86 (06) :1118-1121
[8]   Electron interactions and scaling relations for optical excitations in carbon nanotubes [J].
Kane, CL ;
Mele, EJ .
PHYSICAL REVIEW LETTERS, 2004, 93 (19) :197402-1
[9]   Optical properties of single-wall carbon nanotubes [J].
Kataura, H ;
Kumazawa, Y ;
Maniwa, Y ;
Umezu, I ;
Suzuki, S ;
Ohtsuka, Y ;
Achiba, Y .
SYNTHETIC METALS, 1999, 103 (1-3) :2555-2558
[10]   Raman scattering in carbon nanotubes revisited [J].
Maultzsch, J ;
Reich, S ;
Thomsen, C .
PHYSICAL REVIEW B, 2002, 65 (23) :1-4