Rhodium-containing triple-decker complexes with a central borole ligand

被引：23

作者：

Muratov, Dmitry V.

Petrovskii, Pavel V.

Starikova, Zoya A.

Herberich, Gerhard E.

Kudinov, Alexander R. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 15期

基金：

俄罗斯基础研究基金会;

关键词：

boron; borole; rhodium; sandwich compounds; triple-decker complexes;

D O I：

10.1016/j.jorganchem.2006.03.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Triple-decker complexes with a bridging borole ligand (C4H4BPh)Rh(mu-C4H4BPh)ML (ML = RuCp, 2a; RuCp*, 2b; FeCp*, 3; Co(C4Me4), 4; Ir(cod), 5) were synthesized by stacking reactions of [Rh(C4H4BPh)(2)](-) (1) with cationic [ML](+) fragments. The structures of 2a,6 and (C4H4BPh)Rh(mu-C4H4BPh)Rh(C4H4BPh) (6) were determined by X-ray diffraction. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：3251 / 3259

页数：9

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