Unlock-lock approach to [2] and [3]rotaxanes: Entering of a ring through disulfide linkage that is unlocked by thiol "key"

被引:69
作者
Furusho, Y [1 ]
Hasegawa, T [1 ]
Tsuboi, A [1 ]
Kihara, N [1 ]
Takata, T [1 ]
机构
[1] Univ Osaka Prefecture, Grad Sch Engn, Dept Appl Chem, Osaka 5998531, Japan
关键词
D O I
10.1246/cl.2000.18
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bifunctional secondary ammonium salt bearing disulfide linkage at the center and bulky group at the both termini was mixed with dibenzo-24-crown-8. During reversible cleavage of the disulfide linkage catalyzed by benzenethiol, crown ether entered the disulfide linkage to afford corresponding [2] and [3]rotaxanes.
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页码:18 / 19
页数:2
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