A self-assembly approach to temperature-responsive polymer nanocontainers

被引：20

作者：

Chen, XR ^{[1
]}

Ding, XB ^{[1
]}

Zheng, ZH ^{[1
]}

Peng, YX ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 17期

关键词：

block copolymers; polymer nanocontainers; self-assembly; thermosensitive;

D O I：

10.1002/marc.200400232

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thermosensitive polymer nanocontainers were formed by self-assembly of diblock copolymers poly(2-cinnamoylethyl methaerylate)-block-poly(N-isopropylacrylamide) (PCEMA-block-PNIPAM) and subsequent photo-crosslinking of the PCEMA shells. It was found that the diameter of the nanocontainers ranges from tens of nanometers to thousands of nanometers, depending on the self-assembly conditions. The phase transition of the nanocontainers takes place at 32 degreesC; the structural changes are reversible in a heating and cooling cycle.

引用

页码：1575 / 1578

页数：4

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