Solubility of potassium dichromate in dilute aqueous ethanol solutions in the temperature range 283 K to 303 K

被引:12
作者
Korin, E
Soifer, L
机构
[1] Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105
关键词
D O I
10.1021/je970064y
中图分类号
O414.1 [热力学];
学科分类号
摘要
Solubility data for potassium dichromate in dilute aqueous ethanol solutions were determined at five temperatures (283, 288, 293, 298, and 303) K. The densities of the saturated solutions were also measured. The solubility data (283, 288, 293, and 298) K correlated well with the empirical equation In x(1) = A + Bx(2) + Cx(2)(2) with an precision of +/-1.5% where x(1) and x(2) are the mole fraction of potassium dichromate and ethanol in salt-saturated solutions and A, B, and C are fitted empirical constants depending on the temperature. The results indicate that at ambient temperatures of about 283 to 303 K, addition of less than 0.01 mass fraction of ethanol to an aqueous saturated solution of potassium dichromate caused ''salting out'' in the range between 33 and 43% of the mass of the salt.
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页码:1251 / 1253
页数:3
相关论文
共 14 条
[1]   SEPARATION OF THE SYSTEM NACL-NABR-NAL BY SOLVENTING OUT FROM AQUEOUS-SOLUTION [J].
ALFASSI, ZB ;
ATA, L .
SEPARATION SCIENCE AND TECHNOLOGY, 1983, 18 (07) :593-601
[2]  
BOGOYAVLENSKII PS, 1952, ZH OBSHCH KHIM+, V22, P551
[3]  
BOGOYAVLENSKII PS, 1949, ZH OBSHCH KHIM, V1, P1987
[4]  
FURMAN NH, 1968, STANDARD METHODS CHE
[5]   PRODUCTION OF IRON-FREE ALUM [J].
GEE, EA ;
CUNNINGHAM, WK ;
HEINDL, RA .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1947, 39 (09) :1178-1188
[6]  
HERTZ W, 1929, Z PHYS CHEM, V140, P406
[7]  
HOPPE H, 1968, CHEM PROCESS ENG, V49, P61
[8]  
Kearley R.A., 1964, J. Chem. Eng. Data, V9, P548
[9]   Phase diagram for the system K2Cr2O7+KNO3+H2O in the temperature range 10 degrees C to 40 degrees C [J].
Korin, E ;
Soifer, L .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1997, 42 (03) :508-510
[10]  
Kula MR., 1982, ADV BIOCHEM ENG, V24, P73